Case Study Achieving Sub-ppb TOC Performance in Semiconductor Ultrapure Water Systems with TOCLine AT

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In semiconductor manufacturing, ultrapure water (UPW) quality is fundamental to process stability, wafer yield, and device performance. As process nodes continue to shrink, even trace amounts of Total Organic Carbon (TOC) can affect sensitive surface chemistries, ultimately impacting overall fabrication throughput.

A leading 12-inch semiconductor foundry in China required a trusted TOC reduction solution capable of supporting multiple UPW process streams across its facility. The site selected Nuvonic’s TOCLine AT UV technology, including both standard and High Performance (HP) systems, to achieve extremely low TOC concentrations while maintaining operational reliability and efficient plant operation.

Installed in November 2023, the systems now operate across several critical UPW treatment loops, consistently delivering sub-ppb TOC performance and demonstrating the scalability of the TOCLine AT platform across a wide range of flows and TOC levels.

TOCLine AT40 systems installed in polishing loop 1, achieving 0.5ppb TOC

Design Challenge

Semiconductor fabrication facilities consume large volumes of ultrapure water for wafer rinsing, cleaning and chemical mechanical planarization (CMP). While TOC concentrations measured in only a few parts per billion may appear insignificant, even trace organic contamination can affect process consistency and increase the burden on downstream purification steps.

The customer required a solution capable of:

  • Achieving reliable reduction of low-level organic contamination
  • Maintaining continuous operation
  • Minimising operating and maintenance requirements.
  • Supporting future production requirements without increasing system complexity.
  • High-capacity treatment for multiple UPW process streams.

The Nuvonic Solution

Unlike many industrial water applications, semiconductor UPW systems often need to reduce already-low TOC levels even further. Delivering meaningful TOC reduction at these concentrations requires highly efficient UV technology, precise system design and reliable long-term operation.

Nuvonic supplied three TOC reduction installations within the facility’s UPW infrastructure using a combination of TOCLine AT and TOCLine AT HP systems. Together, the installations treated flows of 40-160 m³/h across both the make-up and polishing loops, exceeding the <1 ppb design requirement despite the presence of urea, a compound that is notoriously difficult to break down.

The Advantage of TOCLine AT HP

  • High-efficiency UV technology.
  • Up to 40% less lamps per system.
  • Reduced maintenance requirements.
  • Lower energy consumption.
  • Reduced lifecycle operating costs.
  • Compact installation footprint.
  • Easy to operate.

How TOCLine AT Reduces Organic Contamination

TOCLine AT systems are engineered with specialized low-pressure UV technology, unique reactor geometries, and high-purity quartz materials for optimal TOC reduction in low oxygen, low TOC conditions.

High-energy, low-wavelength UV light photo-oxidizes water molecules, generating highly reactive hydroxyl radicals. These radicals efficiently break down complex organic compounds into carbon dioxide and small ionic byproducts that are then easily removed by downstream vacuum degasification and mixed-bed ion exchange respectively.

This approach enables effective treatment without introducing additional chemicals into the ultrapure water system, making it particularly suitable for semiconductor manufacturing environments where process purity is critical.

Frequently Asked Questions About TOC Reduction

Explore how UV systems help control organic contaminants and maintain high-purity water for semiconductor, pharmaceutical, and WFI applications.

What TOC levels can TOCLine AT achieve?

TOCLine AT systems are engineered to reduce already low TOC concentrations to sub-ppb levels. Across a wide range of semiconductor UPW installations, the technology has consistently surpassed design targets, reliably achieving TOC concentrations below 0.5-1.0 ppb.

How can I determine the correct TOC reduction system size for my facility?

System sizing depends on flow rate, inlet TOC concentration, target TOC level, dissolved oxygen levels, and overall UPW system configuration. Nuvonic can evaluate site-specific requirements and recommend an optimized solution.

How many UV lamps are required?

Lamp quantity depends on flow rate, TOC loading, and performance requirements. TOCLine AT HP technology can reduce the number of lamps required by up to 40%, helping reduce maintenance and energy costs.

Can the system be retrofitted into existing UPW facilities?
Yes. TOCLine AT systems can be integrated into both new-build semiconductor fabs and existing UPW systems, subject to hydraulic, electrical, and space requirements.
What maintenance is required?

Routine maintenance typically consists of scheduled lamp replacement, quartz sleeve inspection, and periodic performance verification. The reduced lamp count of TOCLine AT HP can significantly lower maintenance requirements.

What flow rates can TOCLine AT support?

The technology is available for a wide range of semiconductor UPW applications, from smaller polishing loops to large central make-up systems. In this project, systems treated flows ranging from 40 to 160 m³/h.

What industries use TOCLine technology?
TOCLine systems are widely used in semiconductor and microelectronics manufacturing, pharmaceutical water systems, and other high-purity water applications where extremely low organic contamination is required.